systemd.directives — Index of configuration directives
This page lists every configuration option, command line switch, constant, etc. anywhere in systemd and then links to the place where it's documented. This is a great entry point to the documentation if you're using it as a pure reference, or if you want to learn more about something but you're not sure what part of systemd it comes from. I only discovered it recently and I wish I had known about it a lot sooner.
This page is, itself, a man page that probably exists on your computer. But the web page's hyperlinking makes it a lot more useful.
